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BiPO4/BiVO4复合材料的制备及可见光催化活性

刘琼君 林碧洲 李培培 高碧芬 陈亦琳

高等学校化学学报2017,Vol.38Issue(1):94-100,7.
高等学校化学学报2017,Vol.38Issue(1):94-100,7.DOI:10.7503/cjcu20160476

BiPO4/BiVO4复合材料的制备及可见光催化活性

Preparation of BiPO4/BiVO4 Composites with High Visible-light Photocatalytic Activity†

刘琼君 1林碧洲 1李培培 1高碧芬 1陈亦琳1

作者信息

  • 1. 华侨大学材料科学与工程学院,厦门361021
  • 折叠

摘要

Abstract

BiPO4/BiVO4 composites were prepared by combining hydrothermal and solvothermal synthetic methods. Field emission scanning electron microscopy( FESEM) and transmission electron microscopy( TEM) revealed that the as-prepared BiVO4 exhibited a truncated bipyramid morphology with high {010}, {110}exposed facets, and that the as-obtained BiPO4 nanoparticles were grown on the surface of BiVO4, leading to the formation of the BiPO4/BiVO4 heterojunction. The transient photocurrent-time behaviors indicated that the formed heterojunction made the transfer and separation of the photo-generated carriers more efficient. The as-synthesized BiPO4/BiVO4 composites exhibited high photocatalytic activities in the degradation of rhoda-mine B under visible-light irradiation. It was found that the sample prepared with a BiPO4/BiVO4 molar ratio of 3∶10 in the reactants showed the best performance.

关键词

钒酸铋/磷酸铋/异质结/可见光催化

Key words

BiVO4/BiPO4/Heterojunction/Visible-light photocatalysis

分类

化学化工

引用本文复制引用

刘琼君,林碧洲,李培培,高碧芬,陈亦琳..BiPO4/BiVO4复合材料的制备及可见光催化活性[J].高等学校化学学报,2017,38(1):94-100,7.

基金项目

国家自然科学基金(批准号50872037)和福建省自然科学基金(批准号2014H0028)资助.? Supported by the National Natural Science Foundation of China(No.50872037) and the Natural Science Foundation of Fujian Province of China( No.2014H0028). ()

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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