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化学交换法分离锂同位素研究进展

肖江 贾永忠 石成龙 王兴权 姚颖 景燕

化工进展2017,Vol.36Issue(1):29-39,11.
化工进展2017,Vol.36Issue(1):29-39,11.DOI:10.16085/j.issn.1000-6613.2017.01.004

化学交换法分离锂同位素研究进展

Research progress of lithium isotope separation by chemical exchange method

肖江 1贾永忠 2石成龙 1王兴权 1姚颖 1景燕1

作者信息

  • 1. 中国科学院青海盐湖研究所,盐湖资源综合高效利用重点实验室,青海西宁 810001
  • 2. 中国科学院大学,北京 100049
  • 折叠

摘要

Abstract

Lithium isotopes(lithium-6 and lithium-7),as important raw materials required in the development of nuclear energy,play a great role in energy,environment,defense-national security, and other fields. The chemical exchange methods for lithium isotopes separation include amalgam exchange process,solvent extraction,chromatography and membrane method. The separation mechanisms,advantage and disadvantage of various lithium isotopes separation methods,have been systematically analyzed,classified and summarized in this paper. The results indicated that lithium isotope separation is related to the bond effect of complexing agent and lithium ionic in the chemical exchange separation system;and lithium amalgam exchange process will be replaced by other non-mercury separation systems due to environmental concerns. In addition,the lithium isotopes separation methods of using solvent extraction,ion exchange chromatographic and membrane are very promising,which all are relatively effective separation . Based on the summarization of the current research progresses,the future researches on the separation of lithium isotopes are highlighted,such as the design and synthetics of new chelating agent,the combination of different separation process and the separation mechanism in different experiment condition.

关键词

锂同位素/化学交换/分离/萃取/机理

Key words

lithium isotope/chemical exchange/separation/extraction/mechanism

分类

化学化工

引用本文复制引用

肖江,贾永忠,石成龙,王兴权,姚颖,景燕..化学交换法分离锂同位素研究进展[J].化工进展,2017,36(1):29-39,11.

基金项目

国家自然科学盐湖专项基金项目(U140710047)。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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