化工进展2017，Vol.36Issue(1)：210-215,6.DOI:10.16085/j.issn.1000-6613.2017.01.027
载体涂层对负载型NiMnO3钙钛矿催化剂催化燃烧VOCs性能的影响
Effect of support coating on the catalytic performance of supported NiMnO3 perovskite catalysts
摘要
Abstract
NiMnO3 perovskite catalysts supported on cordierite honeycomb were synthesized by the citric acid method using Ni(NO3)2·6H2O and Mn(NO3)2. The effect of the coating on the catalytic performance of VOCs in catalytic combustion was investigated. These catalysts were characterized by XRD,SEM,BET,and H2-TPR. The results indicate that the different coating has different effects on the NiMnO3 perovskite catalysts. The Ce0.75Zr0.25O2 coating helps to improve carrier’s specific surface area and the active ingredient’s high temperature stability,and the load is more uniformly dispersed, while the grain size becomes smaller. At the same time,the synergistic effect between Ce0.75Zr0.25O2 coating and NiMnO3 perovskite catalysts can improve the Redox cycle rate of the reaction,and further improve the catalytic performance of the catalysts.关键词
NiMnO3钙钛矿/催化作用/催化剂/催化载体/涂层Key words
NiMnO3 perovskite/catalysis/catalyst/catalyst support/coating分类
化学化工引用本文复制引用
邓磊,李兵,阚家伟,黄超,黄琼,沈树宝,祝社民,陈英文..载体涂层对负载型NiMnO3钙钛矿催化剂催化燃烧VOCs性能的影响[J].化工进展,2017,36(1):210-215,6.基金项目
国家自然科学基金（51172107，51608261）、江苏省高校自然科学研究项目（14KJB430014）、江苏省科技厅重点研发计划（BE2016769）及江苏省环境净化材料工程技术研究中心（ECM）开放课题（KFK1503）项目。 （）
