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生物油蒸馏残渣理化性质及热失重研究

朱谢飞 李凯 马善为 朱锡锋

燃料化学学报2017,Vol.45Issue(1):29-33,5.
燃料化学学报2017,Vol.45Issue(1):29-33,5.

生物油蒸馏残渣理化性质及热失重研究

Physicochemical characteristics and TGA of distillation residues from bio-oil

朱谢飞 1李凯 1马善为 1朱锡锋1

作者信息

  • 1. 中国科学技术大学 安徽省生物质洁净能源重点实验室,中国科学院城市污染物转化重点实验室,安徽 合肥 230026
  • 折叠

摘要

Abstract

The distillation residues from bio-oil and the pyrolysis char obtained at different temperatures were investigated with FT-IR, Raman spectra and TGA. The results show that the distillation residues from bio-oil consist of aliphatic, aromatic and oligosaccharides. The process of thermal weight loss of distillation residues from bio-oil in nitrogen can be separated into three stages. The first is the volatilization of low-boiling point compounds from ambient temperature to 145℃. The second is the pyrolysis, oxidation and polymerization of the heavy compounds at higher temperature and the last is the formation and combustion of coke. The graphitic carbon fraction increases with increasing the carbonization temperature while the disordered carbon amount decreases.

关键词

生物油/蒸馏/热失重

Key words

bio-oil/distillation/thermal weight loss

分类

能源科技

引用本文复制引用

朱谢飞,李凯,马善为,朱锡锋..生物油蒸馏残渣理化性质及热失重研究[J].燃料化学学报,2017,45(1):29-33,5.

基金项目

The project was supported by the Major State Basic Research Development Program of China (973 program,2013CB228103) and the Key Research Program of the Chinese Academy of Sciences (KGZD-EW-304-3).国家重点基础研究发展规划(973计划,2013CB228103)和中国科学院重点部署项目(KGZD-EW-304-3)资助 (973 program,2013CB228103)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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