化工进展2017,Vol.36Issue(2):555-567,13.DOI:10.16085/j.issn.1000-6613.2017.02.022
固体酸催化纤维素水解转化葡萄糖的研究进展
New advances on hydrolysis of cellulose to glucose by solid acid
摘要
Abstract
Solid acid catalysts have been commonly employed for the hydrolysis of cellulose into glucose in recent years due to the ease of product separation and good catalyst recyclability. This paper summarizes the recent advances in the hydrolysis of cellulose using different types of solid acids,such as metal oxides,polymer based acids,sulfonated carbonaceous based acids,heteropoly acids,H-form zeolites,magnetic solid acids,supported metals,solid superacid,and graphene derivative. The catalysts still need to be improved in cellulose contact and active components retainment. The acid strength,acid site density,adsorption of the substance,and micropores of the solid material are all key factors for effective hydrolysis processes. Meanwhile,methods used to promote reaction efficiency,such as the pretreatment of cellulose to reduce its crystallinity and the use of ionic liquids or microwave irradiation to improve the reaction rate,are also discussed. Finally,the potential research trends are also suggested to provide valuable ideas for the hydrolysis of cellulose into glucose in a green,simple,efficient,and inexpensive way.关键词
生物质/聚合物/纤维素/葡萄糖/固体酸/催化Key words
biomass/polymers/cellucose/glucose/solid acids/catalysis分类
化学化工引用本文复制引用
赵博,胡尚连,龚道勇,李会萍..固体酸催化纤维素水解转化葡萄糖的研究进展[J].化工进展,2017,36(2):555-567,13.基金项目
西南科技大学博士基金(15ZX7146)及四川省教育厅科研项目(16ZB0144)。 ()