化工进展2017，Vol.36Issue(2)：672-682,11.DOI:10.16085/j.issn.1000-6613.2017.02.038
生物基芳香平台化合物2,5-呋喃二甲酸的合成研究进展
Research progress on the synthesis of bio-based aromatic platform chemical 2,5-furandicarboxylic acid
摘要
Abstract
2,5-Furandicarboxylic acid(2,5-FDCA) is a promising bio-based aromatic platform chemical for the synthesis of high performance polymers and has been regarded as the most suitable alternative to the petroleum-derived terephthalic acid. The synthesis of 2,5-FDCA through efficient and low cost route has been a hot subject since last decade. In this review article,the popular starting materials,including 5-hydroxymethyl furfural(HMF),furoic acid,furan,diglycolic acid,and hexaric acid,for the fabrication of 2,5-FDCA,are introduced in detail. Perspectives are given based on the comparison of different synthetic routes. The most popular synthetic route is based on HMF by either directly oxidation,noble metal oxidation,non-noble metal oxidation or enzyme catalysis oxidation. This method is considered as the most promising one to achieve large scale preparation of 2,5-FDCA. More importantly,development of novel technology for the conversion of cellulose to glucose is critical to produce large amount of low cost HMF.关键词
2,5-呋喃二甲酸/生物基/平台化合物/合成/进展Key words
2,5-furandicarboxylic acid/bio-based/platform chemical/synthesis/progress分类
化学化工引用本文复制引用
王静刚,刘小青,朱锦..生物基芳香平台化合物2,5-呋喃二甲酸的合成研究进展[J].化工进展,2017,36(2):672-682,11.基金项目
国家自然科学基金（51373194）及国家重点科技支撑项目（2015BAD15B08）。 （）
