高等学校化学学报2017，Vol.38Issue(2)：284-293,10.DOI:10.7503/cjcu20160630
苯基膦酸铈与十溴二苯醚在玻璃纤维增强聚对苯二甲酸乙二酯中的协同阻燃抑烟机理
Synergistic Flame Retardant and Suppression Smoke Mechanism of Cerium Phenylphosphonate and Decabromodiphenyl Oxide in Glass-fiber Reinforced Poly( 1,4-butylene terephthalate) Composites?
摘要
Abstract
Glass fiber reinforced poly(1,4-butylene terephthalate) (PET-GF)/ decabromodiphenyl oxide ( DBDPO)/cerium phenylphosphonate ( CeHPP ) composites were prepared by melt blending. Cone test was employed to investigate the comprehensive combustion behavior and the thermal gravimetric-infrared spectrometry( TG-FTIR) was used to analyze the release amount and component of volatile gases produced during thermal degradation. The scanning electron microtopography( SEM) of char residues was observed, and the elements and contents in char residues were tested by energy dispersive X-ray spectrometer ( EDX ) and X-ray photoelectron spectroscopy( XPS) . The experimental results showed that the compounding of CeHPP and DBDPO in PET-GF restrained the thermo-oxidative degradation of PET-GF/DBDPO/CeHPP composites, retarded the combustion of condensed phases and reduced the smoke release. CeHPP formed the continuous and compact carbon char during combustion, dispersing among the surface of polymer matrix and glass fibers and restricting DBDPO and its decomposition products in condensed phases. Therefore, the synergism flame retardant effects of gaseous phase and condensed phase were achieved, suppressing the smoke release to gaseous phase effectively.关键词
阻燃/抑烟/苯基膦酸稀土/溴系阻燃剂/聚对苯二甲酸乙二醇酯Key words
Flame retardancy/Smoke suppression/Rare earth phenylphosphonate/Brominated flame retardant/Poly(1/4-butylene terephthalate)分类
化学化工引用本文复制引用
郭正虹,方征平,陈超..苯基膦酸铈与十溴二苯醚在玻璃纤维增强聚对苯二甲酸乙二酯中的协同阻燃抑烟机理[J].高等学校化学学报,2017,38(2):284-293,10.基金项目
国家自然科学基金(批准号:51203137)、 浙江省自然科学基金(批准号:LY15E03000008)和宁波市自然科学基金(批准号:2014A610117)资助.? Supported by the National Natural Science Foundation of China(No.51203137), the Zhejiang Provincial Natural Science Foundation of China(No.LY15E030008) and the Ningbo City Natural Science Foundation of China(No.2014A610117). （批准号:51203137）
