中北大学学报（自然科学版）2017，Vol.38Issue(1)：93-98,6.DOI:10.3969/j.issn.1673-3193.2017.01.017
聚苯胺/煤复合材料的制备及腐蚀性能研究
Preparation and Anticorrosion Properties of PANI/Coal Composites Material
摘要
Abstract
The PANI/Coal nanocomposites were synthesized by still-setting method with aniline mono-mer and coal.The composites were added in epoxy and then coated on megnesium alloy coupons.After curing,the PANI/Coal/epoxy anticorroion coatings were obtained.The structure,morphology and properties of samples were characterized by Fourier transformation infrared (FTIR)spectroscopy,scan-ning electron microscopy (SEM),and electrochemical impedance spectroscopy (EIS)in 3.5% NaCl so-lution.The results show the acid doped PANI/Coal composites have been synthesized,and the samples exist as nanorods structure.The corrosion current density and corrosion rate of PANI/Coal composites coatings decrease 2~3 orders compared with pure magnesium alloy.The impedance at low frequency of coatings enhances with the increasing PANI/Coal composites.When the PANI/Coal composites is 20%, the corrosion resistance reaches a best point and with a slow change rate.The anticorrosion properties decrease with the immersion time in 3.5% NaCl solution.The samples with 15% PANI/Coal compos-ites exhibit optimum anticorrsion behaviour.关键词
聚苯胺/煤/环氧树脂/交流阻抗谱/极化曲线Key words
PANI/coal/epoxy resin/EIS/polarization curve分类
化学化工引用本文复制引用
王燕,张晓飞,王珺,刘亚青..聚苯胺/煤复合材料的制备及腐蚀性能研究[J].中北大学学报（自然科学版）,2017,38(1):93-98,6.基金项目
山西省自然科学基金资助项目(2014021018-6) （2014021018-6）
