华东理工大学学报（自然科学版）2017，Vol.43Issue(1)：70-75,6.DOI:10.14135/j.cnki.1006-3080.2017.01.012
Fenton法处理DMF废水及无机阴离子对反应的影响
Fenton Oxidation of DMF Wastewater and Influence of Inorganic Ions on Reaction
邬莎娜 1孙贤波 1刘勇弟 1顾雍 1陈强 1陈颖1
作者信息
- 1. 华东理工大学资源与环境工程学院,国家环境保护化工过程环境风险评价与控制重点实验室,上海 200237
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摘要
Abstract
N,N-Dimethylformamide (DMF)is a universal organic solvent in industry,while it is toxic and non-biodegradable.In this paper,Fenton oxidation was used to treat model DMF wastewater and the influence of pH,reaction time,dose of oxidation agent,as well as the effect of inorganic anions Cl- and SO42- were investigated.The experimental results showed that the optimum conditions with effluent COD<100 mg/L were as follows:when the concentration of DMF was 1 g/L,the dosage of 30% H2 O2 was 40 mL/L,pH=2.0,n(H2 O2 ):n(Fe2+)=3:1,reacting time is 2.5 h.Meanwhile,Cl- had a strong inhibition effect on Fenton oxidation:the COD of effluent increased from 90 mg/L to 250 mg/L with 1 g/L Cl-.The effect of SO42- on the reaction was very small:with a concentration higher than 10 g/L,it could accelerate the reaction to some extent.关键词
DMF废水/Fenton氧化法/无机阴离子Key words
DMF wastewater/Fenton oxidation/inorganic ions分类
资源环境引用本文复制引用
邬莎娜,孙贤波,刘勇弟,顾雍,陈强,陈颖..Fenton法处理DMF废水及无机阴离子对反应的影响[J].华东理工大学学报（自然科学版）,2017,43(1):70-75,6.
