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MgO含量对CaO-Al2O3-MgO-FexO-SiO2-K2O系熔体性质的影响

候朋涛 王丽君 刘仕元 张建坤 周国治

工程科学学报2017,Vol.39Issue(2):215-221,7.
工程科学学报2017,Vol.39Issue(2):215-221,7.DOI:10.13374/j.issn2095-9389.2017.02.008

MgO含量对CaO-Al2O3-MgO-FexO-SiO2-K2O系熔体性质的影响

Influence of MgO content on the thermo-physical properties of CaO-Al2O3-MgO-FexO-SiO2-K2O slags

候朋涛 1王丽君 2刘仕元 3张建坤 2周国治4

作者信息

  • 1. 北京科技大学冶金与生态工程学院, 北京100083
  • 2. 北京科技大学钢铁共性技术协同创新中心, 北京100083
  • 3. 北京科技大学钢铁冶金新技术国家重点实验,北京100083
  • 4. 谦比希铜冶炼有限公司,基特韦23558
  • 折叠

摘要

Abstract

The effects of MgO content on the viscosity and melting behaviors of CaO- Al2O3- MgO- FexO- SiO2- K2O slags were studied. The slag samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) to identify precip-itated phases during the cooling process. Meanwhile, theoretical calculations on the viscosities, solidus/liquidus temperatures as well as quantities of various precipitated phases from the slag system were also carried out by using the FactSage software, which were com-pared with the experimental results. The results indicate that the addition of MgO in slag could cause the increase of melting tempera-ture. The relation between viscosities and temperature presents a breakpoint where the viscosity has a rapid rise, and above this transi-tion temperature, MgO content has little effect on the viscosity. The transition temperature increases with the increasing of MgO con-tent. In the process of slag cooling, the crystalline phases are mainly composed of olivine and spinel. From the calculation results, it could be found that the addition of MgO enhances the precipitates of olivine, which makes the viscosity increase suddenly.

关键词

黏度/熔化温度/氧化镁/析出相

Key words

viscosity/melting temperature/magnesium oxide/precipitated phase

分类

矿业与冶金

引用本文复制引用

候朋涛,王丽君,刘仕元,张建坤,周国治..MgO含量对CaO-Al2O3-MgO-FexO-SiO2-K2O系熔体性质的影响[J].工程科学学报,2017,39(2):215-221,7.

基金项目

中国博士后科学基金委资助项目(2014M560046) (2014M560046)

国家自然科学基金面上资助项目(51374020) (51374020)

工程科学学报

OA北大核心CSCDCSTPCD

2095-9389

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