波谱学杂志2017，Vol.34Issue(1)：25-34,10.DOI:10.11938/cjmr20170104
含苯并咪唑环N-酰腙衍生物的NMR研究
An NMR Study of a Novel N-Acylhydrazone Derivative Containing Benzimidazole Moiety
摘要
Abstract
With 1D NMR, 2D NMR and variable-temperature 1H NMR, the 1H and 13C NMR chemical shift of two isomers (E/trans and E/cis) of a new N-acylhydrazone derivative containing benzimidazole moiety (new compound 1), naming 2-[2-(4-methylphenoxymethyl)-1H-benzimidazol-1-yl]-N'-{[4-(dimetilamino)phenyl]methylene}acetohydrazide, were assigned. Coupling constants and tautomeric ratios of the isomers were determined. Experimental results showed that compound 1 in DMSO-d6 had both E/trans and E/cis isomers, and the ratio of the dominant E/cis isomer was 74.2%.关键词
核磁共振(NMR)/归属/互变异构/酰腙/苯并咪唑Key words
nuclear magnetic resonance (NMR)/assignment/tautomerism/acylhydrazone/benzimidazole分类
数理科学引用本文复制引用
李英俊,李继阳,靳焜,曹欣..含苯并咪唑环N-酰腙衍生物的NMR研究[J].波谱学杂志,2017,34(1):25-34,10.基金项目
辽宁省自然科学基金资助项目(20102126). （20102126）
