杭州师范大学学报（自然科学版）2017，Vol.16Issue(1)：46-50,74,6.DOI:10.3969/j.issn.1674-232X.2017.01.013
环硼硅氧烷的制备与表征
Synthesis and Characterization of Cyclo-borasiloxanes
葛天祥 1李美江1
作者信息
- 1. 杭州师范大学有机硅化学与材料技术教育部重点实验室,浙江 杭州 311121
- 折叠
摘要
Abstract
Cyclo-borasiloxanes were synthesized through a two-step reaction.First, the Phenylboronic acid was reacted with excess amount of dimethyldichlorosilane and thus Si-Cl teminated borasiloxanes were obtained.Subsequently, Si-Cl teminated borasiloxane was used to react with metal oxide and expected products were obtained.The components of the final product were characterized by GC-MS, 1H-NMR ,29Si-NMR , 11B-NMR and FT-IR.The effects of reaction conditions on the reaction were investigated.The results indicated the optimum conditions were as follows, the molar ratio of boronic acid and dimethyldichlorosilane was 1∶6, the reaction temperature was 25 ℃, and the metal oxide was oxidized zinc or magnesium oxide.关键词
环硼硅氧烷/环硅氧烷/苯硼酸/二甲基二氯硅烷Key words
cyclo-borasiloxanes/cyclo-siloxanes/phenylboronic acid/dimethyldichlorosilane分类
化学化工引用本文复制引用
葛天祥,李美江..环硼硅氧烷的制备与表征[J].杭州师范大学学报（自然科学版）,2017,16(1):46-50,74,6.
