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电化学作用对伊利石颗粒凝聚沉降性能的影响

李明明 徐硕 卢冀伟 刘炯天

矿产综合利用Issue(1):125-128,4.
矿产综合利用Issue(1):125-128,4.DOI:10.3969/j.issn.1000-6532.2017.01.029

电化学作用对伊利石颗粒凝聚沉降性能的影响

Effects of the Electrochemical on Coagulation and Sedimentation Performances of Illites in Water

李明明 1徐硕 2卢冀伟 2刘炯天1

作者信息

  • 1. 东北大学资源与土木工程学院,辽宁沈阳110819
  • 2. 黑龙江科技大学矿业工程学院,黑龙江哈尔滨150022
  • 折叠

摘要

Abstract

Illite was one of the main clay minerals in coal.the coal slime water was difficult to settlement,which of viscosity was bigger because of sliming of illite,and not only the coal slime water was difficult to be purified and to be recovered,but also the normal operations of the washing preparation were seriously affected.Aiming at the difficult sedimentation problem of the illite in the water,therefore,this paper,proposed by electrochemical methods to modified the illite,researched the effect of electrochemical action on coagulation and sedimentation behavior of illite,explored a kind of solution to the difficulty settling slurry.The specific experimental process was described as below.this author,firstly modified the illite by using electrochemical methods with calcium chloride as the electrolyte,and tested theζpotential and contact angle of illite under different electric potential with the JS94H electrophoresis apparatus and the JC2000B contact Angle meter,then calculated the electrostatic interaction potential energy,hydration interaction potential energy and total interaction potential energy under different electric potential,finally verified the coagulation and sedimentation performances of illite through the settlement test It were shown by results that by the method of electrochemical modified,the electrostatic interaction potential energy,hydration interaction potential energy and total interaction potential energy between illites,can be effectively reduced,then the sedimentation performance of illite can be better improved.,When electric potential being 2 v/cm,the turbidity of supernatant was 294 NTU that being 34.46% of the no modified illite,the whole settlement model formed by"the side(Edge)surface(Face) "mutual adsorption space truss structure of illite particles,caused to the slower subsidence and the larger turbidity supernatant in the process of coagulation and sedimentation.

关键词

电化学作用/伊利石/凝聚/沉降/EDLVO理论

Key words

Electrochemical action/Illite/Coagulation/Sedimentation/EDLVO theory

分类

矿业与冶金

引用本文复制引用

李明明,徐硕,卢冀伟,刘炯天..电化学作用对伊利石颗粒凝聚沉降性能的影响[J].矿产综合利用,2017,(1):125-128,4.

基金项目

黑龙江省普通高校矿物加工工程重点实验室开放课题(201307) (201307)

矿产综合利用

OA北大核心CSTPCD

1000-6532

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