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CuGa2O4光催化剂的制备、表征与光催化产氢性能研究

张相辉

可再生能源2017,Vol.35Issue(3):354-359,6.
可再生能源2017,Vol.35Issue(3):354-359,6.

CuGa2O4光催化剂的制备、表征与光催化产氢性能研究

Synthesis, characterization and photocatalytic hydrogen production property of CuGa2O4 photocatalyst

张相辉1

作者信息

  • 1. 洛阳师范学院物理与电子信息学院,河南洛阳471022
  • 折叠

摘要

Abstract

CuGa2O4 with a d10 electronic configuration was synthesized via solid-state reaction route.The physical and chemical properties of the product were characterized by X-ray diffraction (XRD),UV-Vis diffusive reflectance spectroscopy (UV-Vis) and scanning electron microscope (SEM).XRD and SEM analysis reveal that CuGa2O4 has an absolute cubic spinel crystalline structure and irregular microparticle shape,respectively.UV-Vis study displays that CuGa2O4 responds to a wide range of solar spectrum.Using glucose as an electron donor,photocatalytic hydrogen production performance over RuO2/CuGa2O4 was investigated.The results showed that photoactivity of hydrogen production over RuO2/CuGa2O4 was improved notably by glucose,and at the same time glucose itself was well degraded.After the initial several hours of induction period,the average hydrogen production rate was 10.59 μmol/h.

关键词

CuGa2O4/尖晶石/产氢/葡萄糖/d10电子构型

Key words

CuGa2O4/spinel/hydrogen production/glucose/d10 electron configuration

分类

能源科技

引用本文复制引用

张相辉..CuGa2O4光催化剂的制备、表征与光催化产氢性能研究[J].可再生能源,2017,35(3):354-359,6.

基金项目

河南省高等学校重点科研项目(15A430001) (15A430001)

洛阳师范学院国家级项目培育基金项目(2014-PYJJ-002). (2014-PYJJ-002)

可再生能源

OA北大核心CSTPCD

1671-5292

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