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基于罗丹明b类的Fe3+荧光探针的合成及其性能研究

黄乔 王宏青 王榆元 罗傲恒 张勤

南华大学学报(自然科学版)2016,Vol.30Issue(4):116-120,128,6.
南华大学学报(自然科学版)2016,Vol.30Issue(4):116-120,128,6.

基于罗丹明b类的Fe3+荧光探针的合成及其性能研究

Synthesis and Properties of Fe3+Fluorescence Probes Based on Rhodamine B

黄乔 1王宏青 1王榆元 1罗傲恒 1张勤1

作者信息

  • 1. 南华大学 化学化工学院,湖南 衡阳421001
  • 折叠

摘要

Abstract

A turn ̄on fluorescent probe BR based on rhodamine for trivalent ferric ion (Fe3+) was synthesized.It was studied that the various factors,such as pH,the water con ̄tent of the solvent,concentration,interfering ion,affected the fluorescence of BR and Fe3+complex.And an approach was developed for the detection of trace amount of Fe3+based on BR as fluorescent probe.The sensing behavior between BR and Fe3+was studied by Job’s ti ̄tration,which showed a 1 ∶ 2 complex formation. In addition,the sensor responded to Fe3+with a linear range of 0~20 μmol/L and a low detection limit of 1.8×10-8 mol/L.

关键词

荧光探针/Fe3+/罗丹明/BR

Key words

fluorescent probe/ferric ion(Fe3+)/rhodamine/BR

分类

化学化工

引用本文复制引用

黄乔,王宏青,王榆元,罗傲恒,张勤..基于罗丹明b类的Fe3+荧光探针的合成及其性能研究[J].南华大学学报(自然科学版),2016,30(4):116-120,128,6.

南华大学学报(自然科学版)

1673-0062

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