燃料化学学报2017，Vol.45Issue(2)：249-256,8.
Ni-Mg复合催化剂催化裂解CH4制氢动力学研究
Kinetic study of the decomposition of methane over Ni-Mg composite catalyst for hydrogen production
摘要
Abstract
The kinetic and deactivation kinetic models of methane catalytic cracking were established based on the data of thermal gravimetric analyzer. The kinetic model of methane catalytic cracking was established by the data of initial hydrogen production rate under the condition of no carbon deposition. The deactivation kinetic model was established by the reduced rate of methane catalytic cracking. The experiment was carried out over Ni-Mg composite catalyst, at the temperature of 535, 585, 635℃ and the methane partial pressures were 104 , 2 × 104, 3×104 Pa. The result shows that the reaction order and activation energy were 0. 5 and 82 kJ/mol, the deactivation order and activation energy were 0. 5 and 118 kJ/mol respectively. The multi-walled carbon nanotubes were all produced under the experimental conditions.关键词
甲烷催化裂解/制氢/Ni-Mg复合催化剂/动力学Key words
methane catalytic cracking/hydrogen production/Ni-Mg composite catalyst/kinetic model分类
化学化工引用本文复制引用
李静漪,王昕晔,张百强,张居兵,卜昌盛,朴桂林..Ni-Mg复合催化剂催化裂解CH4制氢动力学研究[J].燃料化学学报,2017,45(2):249-256,8.基金项目
The project was supported by Science and Technology Major Project of Anhui Province (15czz02045).安徽省科技重大专项计划项目(15czz02045)资助 （15czz02045）
