日用化学工业2017，Vol.47Issue(2)：73-76,117,5.DOI:10.13218/j.cnki.csdc.2017.02.003
一种非离子表面活性剂合成工艺的研究
Synthesis of a kind of nonionic surfactant with a modified catalyst
摘要
Abstract
A catalyst containing Mg-Al composite with both acidic and basic activities and structure similar to that of hydrotalcite was prepared by co-precipitation method under weak alkaline condition using magnesium nitrate crystal and aluminum nitrate crystal as starting materials. The prepared catalyst,after modified with arachidic acid was tested and characterized by X-ray diffraction (XRD),NH 3-temperature programmed desorption (NH 3-TPD)and CO 2-TPD. Then the modified catalyst was applied in ethoxylation of butyl acetate with a fixed bed reactor. Results showed that the prepared and modified catalyst displays conspicuous enhancement of activity for the conversion. The content of targeted products,ethylene glycol butyl ether acetate 1-EBAC and 2-EBAC is higher as well as their carbon number distribution is narrower.关键词
非离子表面活性剂/乙二醇丁醚醋酸酯/水滑石/固定床Key words
nonionic surfactant/ethylene glycol butyl ether acetate (EBAC)/hydrotalcite/fixed bed分类
化学化工引用本文复制引用
张金昌,赵宏斌,孟岩,富扬,刘兆滨,朱建民..一种非离子表面活性剂合成工艺的研究[J].日用化学工业,2017,47(2):73-76,117,5.基金项目
江苏省"博士集聚计划"企业创新人才资助项目(苏人才办[2013]42 号) （苏人才办[2013]42 号）
辽宁省精细化工协同创新中心资助项目(2015) （2015）
扬州市"绿扬金凤计划"优秀博士人才资助项目(yzlyjfjh2013YB085) （yzlyjfjh2013YB085）
