有色金属材料与工程2016，Vol.37Issue(6)：293-300,8.DOI:10.13258/j.cnki.nmme.2016.06.009
金属基氧电极材料催化机理研究进展
Catalysts Machanism for Oxygen Electrode Based on Transition Metal
摘要
Abstract
Fuel cell(FC) as a highly efficient,non-pollution energy conversion device,has attracted much attention.The cathode oxygen reduction reaction(ORR) is one of the most important and critical factors for performance of the battery,and restrict the commercialization.Therefore,it is important to develop a high efficiency electrocatalyst for the ORR and the mechanism of oxygen reduction for the development and commercialization of FC.In this paper,research progresses of the ORR mechanism on metal-based electrocatalysts,have been systematically reviewed on the base of a brief introduction of the FC.The materials include the ptelectrocatalyst,Pt-M electrocatalyst and heteroatom-doped carbon supported metal electrocatalysts.The effort to improve the catalytic activity and durability of the electrocatalysts have been summarized.Reseach on decrease the cost of electrocatalysts and novel non-precious metal electrocatalysts are also reported.The urgent problems and future research focuses on these non-precious metal oxygen reduction electrocatalysts have pointed out.关键词
燃料电池/氧还原反应/催化机理/催化剂/过渡金属Key words
fuel cells/oxygen reduction reaction/catalytic mechanism/catalyst/transition metal分类
信息技术与安全科学引用本文复制引用
张旭,张慧娟..金属基氧电极材料催化机理研究进展[J].有色金属材料与工程,2016,37(6):293-300,8.基金项目
国家自然科学基金项目(21406139) （21406139）
沪江基金项目(B14006) （B14006）
