无机材料学报2017，Vol.32Issue(2)：113-121,9.DOI:10.15541/jim20160255
高镍系三元层状氧化物正极材料容量衰减机理的研究进展
Research Progress on the Capacity Fading Mechanisms of High-Nickel Ternary Layered Oxide Cathode Materials
摘要
Abstract
Owing to advantages of high specific capacity,low cost and environmental friendliness,high-nickel ternary layered oxide cathode materials have received much attention and have been extensively studied over the past ten years.However,its further application is hindered by its structural instability during the cycling,thermal instability and poor storage properties.In order to provide references to tackle the problems that high nickel ternary layered oxide cathode materials faces,the degradation mechanisms of high-nickel ternary layered oxide cathode materials during cycling was summarized and discussed in this review.The degradation mechanisms are categorized as two major factors.One is thermodynamic factors including cation disorder as well as surface reactions,and the other is kinetic factors comprising of micro-cracks formation as well as rearrangement of conductive materials.The modification strategies corresponding to the major mechanisms and the research focusing on initial irreversible capacity loss are also briefly introduced.关键词
高镍系氧化物/三元层状氧化物/正极材料/衰减机理/循环稳定性/综述Key words
high-nickel oxide/ternary layered oxide/cathode material/degradation mechanisms/cycling stability/review分类
信息技术与安全科学引用本文复制引用
李想,葛武杰,王昊,瞿美臻..高镍系三元层状氧化物正极材料容量衰减机理的研究进展[J].无机材料学报,2017,32(2):113-121,9.基金项目
国家自然科学基金(51474196)National Natural Science Foundation of China (51474196) （51474196）
