信阳师范学院学报（自然科学版）2017，Vol.30Issue(1)：114-117,4.DOI:10.3969/j.issn.1003-0972.2017.01.025
5-硝基水杨醛缩乙二胺双希夫碱钴（Ⅲ）配合物的合成、晶体结构及热稳定性研究
Synthesis,Crystal Structure and Thermo Stability of Co (Ⅲ) Complex with Bis-Schiff Base as Ligand
摘要
Abstract
A new supramolecular Co(Ⅲ)-based complex with N,N’-bis-5-nitro-salicylidene)-1,2-diamin-oethane was synthesized by hydrothermal method.The structure of complex was characterized by elemental a-nalysis,IR and single-crystal X-ray diffraction.X-ray structural analysis showed that the ligand employs chelate mode to link with Co(Ⅲ)ion.The three-dimensional network of complex was formed from hydrogen bonding interaction.The result of thermal analysis demonstrated that the title complex had superior thermo stability.In addition,the synthetic conditions of the complex was discussed.关键词
希夫碱/钴(Ⅲ)离子/晶体结构/热稳定性Key words
Schiff base/Co(Ⅲ)ion/crystal structure/thermostability分类
化学化工引用本文复制引用
葛少英,陈小燕,张逢源,宋伟明..5-硝基水杨醛缩乙二胺双希夫碱钴（Ⅲ）配合物的合成、晶体结构及热稳定性研究[J].信阳师范学院学报（自然科学版）,2017,30(1):114-117,4.基金项目
宁夏自然科学基金项目(NZ16035) （NZ16035）
宁夏高等学校科学技术项目(NGY2015026) （NGY2015026）
