北京师范大学学报(自然科学版)2017,Vol.53Issue(1):87-92,6.DOI:10.16360/j.cnki.jbnuns.2017.01.015
廉价金属催化剂可见光催化还原CO2的研究
CO2 reduction with fac-Mn(bpy)(CO)3Br and ZnTPP under visible light irradiation
摘要
Abstract
Visible light-driven photocatalytic reduction of CO2 has been investigated using abundant metal complex (fac-Mn (bpy)(CO)3Br) as catalyst and ZnTPP as photosensitizer.This photocatalytic system demonstrated high efficiency and selectivity for reducing CO2 to CO.Increasing ZnTPP concentration led to enhanced production rate and CO yield.Notably,TONco could reach 97 with a catalyst:photosensitizer concentration ratio of 1∶2.关键词
可见光催化/CO2还原/廉价金属配合物Key words
visible light/CO2 reduction/abundant catalyst分类
化学化工引用本文复制引用
张骏宵,胡长英,陈啊聪,卞兆勇..廉价金属催化剂可见光催化还原CO2的研究[J].北京师范大学学报(自然科学版),2017,53(1):87-92,6.基金项目
国家自然科学基金资助项目(21373032)和KUT grant-in-aid资助项目 (21373032)