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电池材料LiNi0.7Mn0.3O2在熔盐中的生长与电化学性能

范凤松 徐唱 钟盛文 张骞 刘小林

电源技术2017,Vol.41Issue(2):177-180,4.
电源技术2017,Vol.41Issue(2):177-180,4.

电池材料LiNi0.7Mn0.3O2在熔盐中的生长与电化学性能

Research of growth and characterization of powder LiNi0.7Mn0.3O2 in molten salt

范凤松 1徐唱 1钟盛文 1张骞 1刘小林1

作者信息

  • 1. 江西理工大学材料科学与工程学院,江西赣州341000
  • 折叠

摘要

Abstract

The compound LiNi0.7Mn0.3O2 was successfully prepared by molten salt synthesis route using NaCI.They were characterized by X-ray diffraction,SEM,and the charge-discharge cycling.The results show that the sample synthesizing at 850 ℃ for 8 h,the lattice of the sample developed more complete,and the cationic mixed degree was low,so it still had the good electrochemical performance.In initial charge-discharge,the discharge specific capacity could be up to about 180 mAh/g in 2.75 V to 4.2 V voltage range in 0.2 C current and contained 160 mAh/g after 50 cycle times.But for 6 h in the molten salt R=4 at 850 ℃ had the greatest discharge specific capacity,but the platform was narrow and limited application.

关键词

熔盐法/电化学性能/结构/形貌/阳离子混排

Key words

molten-salt method/electrochemical property/structure/morphology/cation mixing

分类

信息技术与安全科学

引用本文复制引用

范凤松,徐唱,钟盛文,张骞,刘小林..电池材料LiNi0.7Mn0.3O2在熔盐中的生长与电化学性能[J].电源技术,2017,41(2):177-180,4.

基金项目

国家自然科学基金(51372104) (51372104)

江西省对外合作项目(20123BDH80016) (20123BDH80016)

江西省科技计划项目(20141BBE50019) (20141BBE50019)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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