电源技术2017，Vol.41Issue(2)：189-191,281,4.
原位制备P(VDF-HFP)/SiO2复合聚合物电解质及其性能研究
In-situ preparation and performance study on P(VDF-HFP)/SiO2 composite polymer electrolyte
摘要
Abstract
P (VDF-HFP)/SiO2 composite polymer electrolyte (CPE) membranes were prepared by phase inversion method,and the desirable CPEs were obtained after being activated into 1.0 mol/LiPF6-EC/DMC/EMC (1 ∶ 1 ∶ 1,v/v/v) liquid electrolytes for 30 min.The physicochemical performance of the as-prepared CPEs was characterized by SEM,XRD,LSV and EIS.The results of SEM indicate that the as-prepared P(VDF-HFP)/SiO2 membrane synthesized via in-situ polymerization presents homogeneous surface and abundant interconnected micro-pores,and the results of XRD show that there may exist interaction forces between SiO2 and polymer matrix.The results of EIS and LSV also show that the ionic conductivity and electrochemical working window of P (VDF-HFP)/SiO2 CPE membrane can reach 3.134 x 10-3 S/cm and 5.0 V,respectively.And the interfacial impedance is directfy dropped from 920 Ω to 850 Ω compared to the as-prepared composite membrane with adding SiO2.关键词
原位/聚合物电解质/SiO2/P(VDF-HFP)Key words
in-situ/polymer electrolyte/SiO2/P(VDF-HFP)分类
信息技术与安全科学引用本文复制引用
王脂胭,缪畅,颜学敏,肖围..原位制备P(VDF-HFP)/SiO2复合聚合物电解质及其性能研究[J].电源技术,2017,41(2):189-191,281,4.基金项目
国家自然科学青年基金资助项目(51404038) （51404038）
湖北省教育厅科学研究计划项目(B2016040) （B2016040）
湖北省大学生创新创业训练计划项目(104892014018) （104892014018）
