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Li2MnO3活化机理及其影响因素的研究进展

赵世玺 郭双桃 邓玉峰 熊凯 徐亚辉 南策文

硅酸盐学报2017,Vol.45Issue(4):495-503,9.
硅酸盐学报2017,Vol.45Issue(4):495-503,9.DOI:10.14062/j.issn.0454-5648.2017.04.06

Li2MnO3活化机理及其影响因素的研究进展

Progress on Mechanism and Impacting Factor of Electrochemical Activation for Li2MnO3

赵世玺 1郭双桃 1邓玉峰 2熊凯 1徐亚辉 3南策文3

作者信息

  • 1. 清华大学深圳研究生院新材料研究所,广东深圳 518055
  • 2. 清华大学材料学院,北京 100084
  • 3. 淮安新能源材料技术研究院,江苏淮安 223005
  • 折叠

摘要

Abstract

Li-rich Mn-based cathode materials are considered as the most promising candidate for the next-generation lithium ion batteries due to their high capacity, high voltage and low cost. However, their application is still restricted due to the presence of some problems like voltage decay, capacity loss, spinel-like transformation,etc. which are closely related to the activation of Li2MnO3 part. In this review, recent development on the structural information and activation mechanism of Li2MnO3 was summarized. The affecting factors (i.e., temperature,sintering procedure and particle size) and the corresponding mechanism were discussed. In addition, the development and application of Li-rich cathode materials were also prospected.

关键词

锂离子电池/正极材料/锰酸锂/活化机理

Key words

lithium ion battery/cathode material/lithium manganate/activation mechanism

分类

能源科技

引用本文复制引用

赵世玺,郭双桃,邓玉峰,熊凯,徐亚辉,南策文..Li2MnO3活化机理及其影响因素的研究进展[J].硅酸盐学报,2017,45(4):495-503,9.

基金项目

深圳市基础研究项目(JCYJ20140509172959973). (JCYJ20140509172959973)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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