硅酸盐学报2017,Vol.45Issue(4):579-584,6.DOI:10.14062/j.issn.0454-5648.2017.04.19
介孔炭-HY分子筛复合型脱硫吸附剂的制备与性能
Preparation and Performance of OMC-HY Composite Desulfurization Adsorbent
摘要
Abstract
The ordered mesoporous carbon (OMC)-HY zeolite composite material was synthesized, and the composite material was characterized X-ray diffraction, specific surface area measurement by nitrogen adsorption stripping, Fourier infrared spectroscopy, NH3-temperature programmed desorption, scanning electron microscopy and transmission electron microscopy, respectively. The result shows that the OMC-HY composite material exhibits a micro-mesoporous pore size distribution, and the specific surface area of the composite material increases when acid increases. The composite material can be used as an adsorbent to remove dibenzothiophene. It is indicated that the thermodynamic process of OMC-HY composite material follows the Langmuir adsorption isotherm models, and the adsorption kinetics follows the pseudo-second-order reaction model.关键词
复合材料/吸附脱硫/动力学/热力学Key words
composite materials/adsorption desulfurization/dynamics/thermodynamics分类
化学化工引用本文复制引用
张志芳,杨丽娜,白金,李剑..介孔炭-HY分子筛复合型脱硫吸附剂的制备与性能[J].硅酸盐学报,2017,45(4):579-584,6.基金项目
辽宁省科学技术厅项目(2013020097) (2013020097)
辽宁省教育厅项目(LJQ2015062,L2015296) (LJQ2015062,L2015296)
抚顺市科技计划项目(FSKJHT201376). (FSKJHT201376)