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ZSM-5小颗粒团聚体的制备及其MTP催化性能研究

安良成 刘素丽 江永军 邵光涛 李增杰 袁华 梁雪美 袁炜 罗春桃

宁夏大学学报(自然科学版)2017,Vol.38Issue(1):47-51,5.
宁夏大学学报(自然科学版)2017,Vol.38Issue(1):47-51,5.

ZSM-5小颗粒团聚体的制备及其MTP催化性能研究

Study on Synthesis of Zeolite ZSM-5 Small Particle Aggregates and Their Catalytic Performance for Methanol to Propylene Reaction

安良成 1刘素丽 1江永军 1邵光涛 1李增杰 1袁华 1梁雪美 1袁炜 1罗春桃1

作者信息

  • 1. 神华宁夏煤业集团有限责任公司煤制油化工研发中心,宁夏银川 750411
  • 折叠

摘要

Abstract

Taking macroporous silica gel and NaAlO2 as raw materials and TPABr as template,the ZSM-5 small particle aggregates were synthesized with hydrothermal crystallization method.The structures were characterized with XRD,SEM,NH3-TPD,N2 physical absorption,XRF,and TG methods.The article also investigates the catalytic performance of their methanol to propylene (MTP) reaction.Comparing with the samples prepared according to the documents,the small particle aggregates of ZSM-5 have richer mesoporous and better anti-carbon performance,perform better propylene selectivity and stability in MTP reaction,their average selectivity of propylene is 47.27%,and the conversion per pass turns to 300 h.

关键词

ZSM-5分子筛/团聚体/MTP反应

Key words

ZSM-5 zeolite molecular sieve/aggregate/MTP reaction

分类

化学化工

引用本文复制引用

安良成,刘素丽,江永军,邵光涛,李增杰,袁华,梁雪美,袁炜,罗春桃..ZSM-5小颗粒团聚体的制备及其MTP催化性能研究[J].宁夏大学学报(自然科学版),2017,38(1):47-51,5.

基金项目

国家国际科技合作专项基金资助项目(2015DFA40660) (2015DFA40660)

宁夏大学学报(自然科学版)

OACSTPCD

0253-2328

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