燃料化学学报2017，Vol.45Issue(3)：311-316,6.
纯四方相硫化氧化锆催化剂的制备及其生物柴油合成应用研究
Synthesis of tetragonal sulfated zirconia via a novel route for biodiesel production
摘要
Abstract
The sulfated zirconia was prepared by directly impregnating ammonium persulphate on the crystalline zirconia and followed by the calcination temperatures of 300-500℃.The structural properties of the catalysts were characterized by X-ray diffraction (XRD), N2 adsorption-desorption, ammonia temperature programmed desorption (NH3-TPD), Fourier transform infrared spectroscopy (FT-IR) and a scanning electron microscope (SEM) equipped with an energy dispersive spectroscope (EDS).The experiment results demonstrated that the catalysts presented the tetragonal structure of zirconia and high crystallinity.The catalyst calcined at 500℃ possessed the highest sulfur content and acidic sites in the catalysts.The catalyst exhibited high catalytic activity in transesterification of soybean oil with methanol.The yield of biodiesel achieved 84.6% because of the preferable super-acid sites on the surface of the catalyst.关键词
四方相硫化锆/浸渍/晶体氧化锆/酯交换反应/生物柴油Key words
tetragonal sulfated zirconia/impregnating/crystalline zirconia/transesterification/biodiesel分类
化学化工引用本文复制引用
石国亮,于峰,闫晓亮,李瑞丰..纯四方相硫化氧化锆催化剂的制备及其生物柴油合成应用研究[J].燃料化学学报,2017,45(3):311-316,6.基金项目
国家自然科学基金(21376157, 21406153),山西省青年科学研究基金(2013021008-3)和太原科技大学校博士科研启动基金(20162017)资助 The project was supported by the National Natural Science Foundation of China (21376157, 21406153), Shanxi Province Science Foundation for Youths (2013021008-3)and Research Fund for the Doctoralcandidate of Taiyuan University of Science and Technology (20162017). （21376157, 21406153）
