燃料化学学报2017，Vol.45Issue(3)：317-322,6.
ZnCl2溶液中微波辅助SnCl4催化纤维素制备5-HMF
Preparation of 5-HMF from cellulose catalyzed by SnCl4 under microwave in ZnCl2 solution
摘要
Abstract
Conversion of cellulose into 5-hydroxymethylfurfural (5-HMF) catalyzed by SnCl4 in ZnCl2 solution with microwave was studied.The effects of microwave power, cellulose content, concentration of ZnCl2, reaction time and the molar ratio of SnCl4 to cellulose on the yields of 5-HMF were investigated.The results showed that under the optimum reaction condition of 1.0g cellulose dissolved in 100mL 70% ZnCl2 solution, the molar ratio of SnCl4 to cellulose of 2∶1, the microwave power of 420W, and the reaction time of 9min, the yield of 5-HMF reaches 39.4%.关键词
微波/纤维素/ZnCl2溶液/SnCl4/5-HMFKey words
microwave/cellulose/ZnCl2 solution/SnCl4/5-HMF分类
化学化工引用本文复制引用
张强,喻蓬秋,李林,乐治平..ZnCl2溶液中微波辅助SnCl4催化纤维素制备5-HMF[J].燃料化学学报,2017,45(3):317-322,6.基金项目
国家自然科学基金(21466021)资助 The project was supported by the National Natural Science Foundation of China (21466021). （21466021）
