燃料化学学报2017,Vol.45Issue(3):362-369,8.
Fe3O4/RGO复合材料的制备及其电化学性能研究
Synthesis of Fe3O4/RGO composites and their electrochemical performance
摘要
Abstract
With reduced graphene oxide (RGO) as the precursor, Fe3O4/RGO composites were synthesized via a hydrothermal method combined with annealing treatment;the crystalline phase, microstructure and component of Fe3O4/RGO composites were characterized by XRD, SEM, TEM and Raman spectra.As a new type of lithium battery electrode materials, their electrochemical performance and the corresponding performance enhanced mechanism were investigated by the CV and EIS tests.The results indicate that high loading Fe3O4/RGO anodes after charge-discharge 60 cycles show high reversible capacities of 709mAh/g at 200mA/g and 479mAh/g at 600mA/g, with a very good rate performance.Compared with the Fe3O4 electrodes, Fe3O4/RGO electrodes exhibit better electrochemical performance, which is associated with a synergy between the stable RGO matrix and its good conductivity;such a nano-sized configuration may not only facilitate the electron conduction but also help to maintain the structural integrity of active materials.关键词
纳米Fe3O4/还原氧化石墨烯/储锂性能/电化学性能/锂离子电池/负极材料Key words
Fe3O4 nanoparticles/reduced graphene oxide (RGO)/lithium storage property/electrochemical performance/lithium ion batteries/anode materials分类
化学化工引用本文复制引用
关贵清,邹明忠,冯倩,林建平,黄志高,颜桂炀..Fe3O4/RGO复合材料的制备及其电化学性能研究[J].燃料化学学报,2017,45(3):362-369,8.基金项目
国家自然科学基金(21473096, 21603112),福建省省属高校专项课题(JK2014055)和宁德市科技计划项目(20140218,20150169)资助 The project was supported by the National Natural Science Foundation of China (21473096, 21603112), the Special Project for Fujian Provincial Universities (JK2014055)and the Research Project of Science and Technology of Ningde City (20140218, 20150169). (21473096, 21603112)