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Fe3O4/RGO复合材料的制备及其电化学性能研究

关贵清 邹明忠 冯倩 林建平 黄志高 颜桂炀

燃料化学学报2017,Vol.45Issue(3):362-369,8.
燃料化学学报2017,Vol.45Issue(3):362-369,8.

Fe3O4/RGO复合材料的制备及其电化学性能研究

Synthesis of Fe3O4/RGO composites and their electrochemical performance

关贵清 1邹明忠 2冯倩 2林建平 1黄志高 2颜桂炀3

作者信息

  • 1. 宁德师范学院 物理与电气工程系, 福建 宁德 352100
  • 2. 福建师范大学物理与能源学院, 福建省量子调控与新能源材料重点实验室, 福建 福州 350117
  • 3. 宁德师范学院 化学系, 福建 宁德 352100
  • 折叠

摘要

Abstract

With reduced graphene oxide (RGO) as the precursor, Fe3O4/RGO composites were synthesized via a hydrothermal method combined with annealing treatment;the crystalline phase, microstructure and component of Fe3O4/RGO composites were characterized by XRD, SEM, TEM and Raman spectra.As a new type of lithium battery electrode materials, their electrochemical performance and the corresponding performance enhanced mechanism were investigated by the CV and EIS tests.The results indicate that high loading Fe3O4/RGO anodes after charge-discharge 60 cycles show high reversible capacities of 709mAh/g at 200mA/g and 479mAh/g at 600mA/g, with a very good rate performance.Compared with the Fe3O4 electrodes, Fe3O4/RGO electrodes exhibit better electrochemical performance, which is associated with a synergy between the stable RGO matrix and its good conductivity;such a nano-sized configuration may not only facilitate the electron conduction but also help to maintain the structural integrity of active materials.

关键词

纳米Fe3O4/还原氧化石墨烯/储锂性能/电化学性能/锂离子电池/负极材料

Key words

Fe3O4 nanoparticles/reduced graphene oxide (RGO)/lithium storage property/electrochemical performance/lithium ion batteries/anode materials

分类

化学化工

引用本文复制引用

关贵清,邹明忠,冯倩,林建平,黄志高,颜桂炀..Fe3O4/RGO复合材料的制备及其电化学性能研究[J].燃料化学学报,2017,45(3):362-369,8.

基金项目

国家自然科学基金(21473096, 21603112),福建省省属高校专项课题(JK2014055)和宁德市科技计划项目(20140218,20150169)资助 The project was supported by the National Natural Science Foundation of China (21473096, 21603112), the Special Project for Fujian Provincial Universities (JK2014055)and the Research Project of Science and Technology of Ningde City (20140218, 20150169). (21473096, 21603112)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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