物理化学学报2017,Vol.33Issue(2):295-304,10.DOI:10.3866/PKU.WHXB201610172
固溶体光催化材料的研究进展
Development of Solid Solution Photocatalytic Materials
摘要
Abstract
Traditional semiconductor photocatalysts with a wide band gap can achieve visible light responses through element doping.However,the localized levels introduced by impurities may act as recombination centers of charge carriers,which may lower the photocatalytic activity of the doped materials.The solid solution method can realize precise regulation of the band gap and band edge positions of materials to obtain an optimal balance between their optical absorption and redox potentials.The solid solution method is therefore an effective approach to improve the photocatalytic performance of semiconductor materials.In the present review,considering our recent research,we briefly discuss the latest progress of the solid solution method to tune the band gap and band edge positions of photocatalytic materials as well as examining its influence on carrier separation and migration properties.Finally,challenges and prospects for further development of this method are presented.关键词
光催化材料/掺杂/固溶体/电子结构/载流子分离Key words
Photocatalytic material/Doping/Solid solution/Electronic structure/Carrier separation分类
化学化工引用本文复制引用
荆涛,戴瑛..固溶体光催化材料的研究进展[J].物理化学学报,2017,33(2):295-304,10.基金项目
The project was supported by the National Key Basic Research Program of China (973) (2013CB632401),National Natural Science Foundation of China (21333006,11374190),and Taishan Scholar Program of Shandong Province,China.国家重点基础研究发展规划(973) (2013CB632401),国家自然科学基金(21333006,11374190)和山东省泰山学者计划资助项目 (973)