厦门大学学报（自然科学版）2017，Vol.56Issue(2)：150-155,6.DOI:10.6043/j.issn.0438-0479.201605007
一种新的铜硼磷酸盐K0.325(H3O)0.675Na2H0.68Cu4[B2P4(B0.84P0.16)O20]Cl的合成与表征
Synthesis and Characterization of a New Copper Borophosphates Compound K0.325(H3O)0.675Na2H0.68Cu4[B2P4(B0.84P0.16)O20]Cl
摘要
Abstract
In this paper,the synthetic chemistry of copper boron phosphates system has been explored.A new copper borophosphates compound K0.325(H3O)0.675Na2H0.68Cu4[B2P4(B0.84P0.16)O20]Cl with special boron phosphorus oxygen structural unit was synthesized by phosphoric acid solvothermal method.And the compound has been characterized by single-crystal and powder X-ray diffraction,NMR and FT-IR.Single-crystal structure analysis reveals that the special boron phosphorus oxygen structural unit is constructed by the connection of groups by partial substitution of groups,which has been proved using NMR.关键词
铜硼磷酸盐/磷酸溶剂热法/特殊硼磷氧结构单元/核磁共振Key words
copper borophosphates/phosphoric acid solvothermal method/special boron phosphorus oxygen structural unit/NMR分类
数理科学引用本文复制引用
陈婷荷..一种新的铜硼磷酸盐K0.325(H3O)0.675Na2H0.68Cu4[B2P4(B0.84P0.16)O20]Cl的合成与表征[J].厦门大学学报（自然科学版）,2017,56(2):150-155,6.
