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铁基粉末冶金零件电镀前二次水基防锈溶液的封孔技术研究

向可友 徐良 刘梦兰 高荣龙

表面技术2017,Vol.46Issue(4):22-26,5.
表面技术2017,Vol.46Issue(4):22-26,5.DOI:10.16490/j.cnki.issn.1001-3660.2017.04.005

铁基粉末冶金零件电镀前二次水基防锈溶液的封孔技术研究

Pore Sealing Technology of Water-based Antirust Solution before Elec- troplating of Iron-base Powder Metallurgy Parts

向可友 1徐良 1刘梦兰 1高荣龙1

作者信息

  • 1. 珠海市玛斯特五金塑胶制品有限公司,广东 珠海 519175
  • 折叠

摘要

Abstract

Iron-base powder metallurgy parts are provided with loose and porous structure, hence acid, alkali and salt may be left in pores of the parts easily during such process as pretreatment, electroplating and passivation. In such case, the plated parts were easily subject to corrosion resistance decrease or coating peeling off. Therefore, sealing pretreatment of pores in iron-base powder metallurgy parts can efficiently improve the corrosion resistance and coating adhesion. A special water-based antirust sealing solution for iron-base powder metallurgy parts was applied to the first sealing before pores pretreatment and second sealing after pretreatment. During the first sealing process, inhibitor and passivation agent in this special antirust solution could diffuse and permeate through the pores, and result in chemical adsorption, passivation or precipitation in pores, which could reduce or avoid acid, alkali and salt residue during pretreatment. During the second process, the passivation and sealing effects of the parts were further improved. For white passivated zinc nickel alloy coatings not subject to second sealing treatment with antirust water solution (barrel plating parts), slight corrosion occurred on the surface after 96 h salt spray test; for the Zn-Ni alloy coating subject to first sealing treatment, slight corrosion occurred after 120 h; for the Zn-Ni alloy coating subject to second sealing treatment, slight corrosion occurred after 240 h. The corrosion resistance and adhesion property are both signifi-cantly improved by performing the sealing processes, Zn-Ni coating electroplating and coating passivation.

关键词

铁基粉末冶金零件/水基防锈溶液/孔隙/封闭/电镀Zn-N合金/腐蚀

Key words

iron-base powder metallurgy parts/water-based antirust solution/pores/sealing/electroplated Zn-N coating/corrosion

分类

矿业与冶金

引用本文复制引用

向可友,徐良,刘梦兰,高荣龙..铁基粉末冶金零件电镀前二次水基防锈溶液的封孔技术研究[J].表面技术,2017,46(4):22-26,5.

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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