华中师范大学学报（自然科学版）2017，Vol.51Issue(2)：184-188,5.
安替比林衍生金属Ni(Ⅱ)配合物的合成、表征及性质研究
Synthesis, characterization and properties of the antipyrine derivative metal nickel (Ⅱ) complex
摘要
Abstract
A new dinuclear nickel(Ⅱ) complex,[Ni2(L4)4Cl4 · (H2O)2]· (CH3CH2OH)2 (L4 =pyri-dine-4-carboxaldehyde and 4-aminoantipyrine) coordination has been successfully synthesized by solvothermal treatment of NiCl2 · 6H2O with L4.The structure and property of the complex has been characterized by single-crystal X-ray diffraction,IR,Raman spectroscopy,elemental analysis and TG.The results show that the complex crystallizes in the monocle-nic space group P21/c with cell parameters:a=6.4266(4)(A),b=33.732(2)(A),c=17.3649(12)(A),α=90°,β=89.708(1)°,γ=90°;V=3764.4(4)(A)3,Z=2.The complex has a high thermal stability.关键词
吡啶类希夫碱/溶剂热法/双核Ni(Ⅱ)配合物/晶体结构Key words
pyridine class schiff base/solvothermal method/dinuclear nickel(Ⅱ) complex/crystal structure分类
化学化工引用本文复制引用
毛仁群,邹晓青,喻情,马丽,刘畅,庞海霞,袁曦明..安替比林衍生金属Ni(Ⅱ)配合物的合成、表征及性质研究[J].华中师范大学学报（自然科学版）,2017,51(2):184-188,5.基金项目
湖北省科学技术厅项目(2014cfb600) （2014cfb600）
青年湖北省楚天学者基金项目(4032401) （4032401）
2015年省级大学生创新创业训练计划项目(201510500020) （201510500020）
湖北工业大学博士基金项目(BSQD2016020). （BSQD2016020）
