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新型有机硅阻燃PBT的研究

何伟壮 周文君 徐存进

杭州师范大学学报(自然科学版)2017,Vol.16Issue(2):123-129,7.
杭州师范大学学报(自然科学版)2017,Vol.16Issue(2):123-129,7.DOI:10.3969/j.issn.1674-232X.2017.02.002

新型有机硅阻燃PBT的研究

On Novel Organosilicon Flame Retardant PBT

何伟壮 1周文君 1徐存进1

作者信息

  • 1. 杭州师范大学材料与化学化工学院,浙江 杭州 310036
  • 折叠

摘要

Abstract

Special silicone-based flame retardant with superfine high activity magnesium hydroxide carrier (FRX-210) was selected to prepare halogen-free flame retardant poly (butylene terephthalate) (PBT).Additionally,oxygen index analyzer and cone calorimeter were used to investigate the flame retardant effect on PBT when FRX-210 was added.The results showed that adding FRX-210 could significantly increase the limiting oxygen index (LOI) of PBT,as adding 30% FRX-210 could increase the LOI of PBT from 22.1% to 27.5%,and adding 20% FRX-210 and 10% boron phosphate could help the LOI of PBT reach 36.0%.By using FRX-210,thermal degradation rate of PBT reduced,the amount of char residue increased,and heat release rate and smoke release rate decreased during combustion,so as to improve the flame retardancy of PBT.

关键词

聚对苯二甲酸丁二醇酯(PBT)/有机硅阻燃剂/阻燃性能/热降解

Key words

poly (butylene terephthalate)/organosilicon flame retardant/flame retardancy/thermal degradation

分类

化学化工

引用本文复制引用

何伟壮,周文君,徐存进..新型有机硅阻燃PBT的研究[J].杭州师范大学学报(自然科学版),2017,16(2):123-129,7.

基金项目

浙江省自然科学基金项目(LY14E030009) (LY14E030009)

浙江省公益技术应用研究项目(2015C31146). (2015C31146)

杭州师范大学学报(自然科学版)

OACSTPCD

1674-232X

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