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电化学处理对神木煤显微组分表面结构及可浮性的影响研究

赵伟 杨志远 李振 周安宁

燃料化学学报2017,Vol.45Issue(4):400-407,8.
燃料化学学报2017,Vol.45Issue(4):400-407,8.

电化学处理对神木煤显微组分表面结构及可浮性的影响研究

Influence of electrochemical treatment on surface structure and flotability of Shenmu coal macerals

赵伟 1杨志远 2李振 1周安宁2

作者信息

  • 1. 西安科技大学 化学与化工学院,陕西 西安 710054
  • 2. 国土资源部 煤炭资源勘查与综合利用重点实验室, 陕西 西安 710021
  • 折叠

摘要

Abstract

The effect of the electrochemical treatment on the surface structure and flotability of the macerals in Shenmu coal was studied, which aimed to provide a theoretical foundation for the separation by electrochemical flotation. The influence of anode and cathode on the surface structure, surface potential and wettability of Shenmu vitrinite and inertinite was investigated. The results show that the electrochemical treatment has a significant effect on the oxygen-containing functional groups of coal macerals such as -OH, -COOH, etc. The surface zeta potential of macerals moves towards the electronegativity and the wettability of macerals increases when the treatment is conducted with electrochemical anode. However, the surface zeta potential of macerals moves towards the electropositivity and the wettability decreases when the electrochemical cathode is used. The variation trend of contact angle for the vitrinite treated with electrochemical anode is more obvious, while the inertinite treated with electrochemical cathode is more conspicuous.

关键词

电化学/煤岩显微组分/表面结构/表面电位/润湿性

Key words

electrochemical/coal maceral/surface structure/surface potential/wettability

分类

化学工程

引用本文复制引用

赵伟,杨志远,李振,周安宁..电化学处理对神木煤显微组分表面结构及可浮性的影响研究[J].燃料化学学报,2017,45(4):400-407,8.

基金项目

The project was supported by the National Natural Science Foundation of China (51404194), Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Land and Resources of China ( KF2015-2 ) and Cultivation Fund of Xi ' an University of Science and Technology (201622).国家自然科学基金(51404194),国土资源部煤炭资源勘查与综合利用重点实验室项目(KF2015-2)和西安科技大学培育基金(201622)资助 (51404194)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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