印染助剂2017,Vol.34Issue(3):9-12,4.
氟代丙烯酸酯共聚物的合成及应用
Synthesis and application of fluorinated acrylate copolymer
摘要
Abstract
The fluorinated acrylate copolymer was synthesized by the reaction of unsaturated monomer and acrylic monomer under normal pressure,and the linen fabric was finished with the fluorinated acrylate copolymer.The structures of the latexes and their films as well as the applied properties of flax fabrics after finishing were studied by means of Fourier transform infrared spectroscopy,transmission electron microscopy and X-ray photoelectron spectroscopy.The results show that nanoscale fluorinated acrylate copolymer with core-shell structure could be synthetised by semi-continuous seed emulsion copolymerization.The finished fabric by the emulsion became smooth and flat.The tensile strength of the finished fabric was increased significantly.And water and air permeability decreased slightly.The contact angles of the films to water and hexadecane were 98.32° and 65.58°,respectively.关键词
有机氟/丙烯酸酯/亚麻织物/整理剂/疏水性/疏油性Key words
organic fluorine/acrylate ester/flax fabric/finishing agent/hydrophobicity/lipophobic分类
化学化工引用本文复制引用
隋智慧,杨康乐,陈杰,赵欣..氟代丙烯酸酯共聚物的合成及应用[J].印染助剂,2017,34(3):9-12,4.基金项目
黑龙江省自然科学基金项目(E201468) (E201468)
黑龙江省教育厅科学研究项目(12531768) (12531768)
齐齐哈尔大学研究生创新科研项目(YJSCX2016-ZD04) (YJSCX2016-ZD04)