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红霉素分子印迹二维光子晶体水凝胶传感器的研究

高敏君 刘根起 薛亚峰 陈小娟 师维江 范晓东

分析化学2017,Vol.45Issue(5):727-733,7.
分析化学2017,Vol.45Issue(5):727-733,7.DOI:10.11895/j.issn.0253-3820.160771

红霉素分子印迹二维光子晶体水凝胶传感器的研究

Erythromycin Molecularly Imprinted Two-dimensional Photonic Crystal Hydrogel Sensor

高敏君 1刘根起 1薛亚峰 1陈小娟 1师维江 1范晓东1

作者信息

  • 1. 西北工业大学理学院应用化学系,陕西省高分子科学与技术重点实验室,西安710129
  • 折叠

摘要

Abstract

A molecularly imprinted two-dimensional photonic crystal hydrogel sensor was developed with erythromycin as imprinted molecule, polystyrene two-dimensional photonic crystal as templates, methanol as solvent, methacrylic acid as monomers and ethylene glycol dimethylacrylate as cross-linkers.The imprinted molecule was removed by methanol/acetic acid (9∶1, V/V).The results showed that the diameter of Debye ring increased 6 mm when the concentration of EM changed from 0 to 1×10-6 mol/L.Namely the lattice spacing decreased 30 nm.In addition, the diameter of Debye ring only increased 1.5 and 2.0 mm when the hydrogel immersed in 1×10-6 mol/L roxithromycin (RM) or erythromycin ethylsuccinate (EEs) solution.The result indicated that the sensor had high selectivity and could be used in determination of erythromycin with low cost and easy operation.

关键词

分子印迹/二维光子晶体/水凝胶/红霉素/传感器

Key words

Molecularly imprinting/Two-dimensional photonic crystal/Hydrogel/Erythromycin/Sensor

引用本文复制引用

高敏君,刘根起,薛亚峰,陈小娟,师维江,范晓东..红霉素分子印迹二维光子晶体水凝胶传感器的研究[J].分析化学,2017,45(5):727-733,7.

基金项目

本文系西北工业大学研究生创意创新种子基金(No.Z2016168)资助 (No.Z2016168)

分析化学

OA北大核心CSCDCSTPCDSCI

0253-3820

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