火炸药学报2017，Vol.40Issue(2)：19-23,32,6.DOI:10.14077/j.issn.1007-7812.2017.02.003
RDX基可燃材料的热力学性能,非等温反应动力学及安全性研究
Thermodynamic Properties, Non-isothermal Reaction Kinetics and Safety of RDX-based Combustible Materials
杨伟涛 1张玉成 1刘少武 1张远波 1王琼林1
作者信息
- 1. 西安近代化学研究所,陕西 西安 710065
- 折叠
摘要
Abstract
TG and DSC were used to investigate the thermal behaviors of the RDX-based microcellular combustible materials.The exothermic reaction kinetics was studied by non-isothermal DSC.The Kissinger and Ozawa methods were applied to investigate the thermal decomposition kinetics of combustible materials.The compatibility between components was evaluated based on the Kissinger method.The evaluation of heat resistance and moisture absorption were conducted.The results show that the decomposition is viewed as a two-step reaction,the first stage is the endothermic melting reaction without mass loss,the second stage is the exothermic reaction with mass loss.The activation energy obtained by Kissinger and Ozawa methods is similar,and activation energies of combustible materials are lower than that of pure RDX.The compatibility between binders (PMMA and CA) and RDX is good,level 1.The critical temperature of thermal explosion is similar to RDX.Other characteristics of new microcellular combusitble materials are superior to the old ones.关键词
可燃材料/热分解性能/热分解动力学/RDXKey words
combustible materials/thermal decomposition performance/thermal decomposition kinetics/RDX分类
军事科技引用本文复制引用
杨伟涛,张玉成,刘少武,张远波,王琼林..RDX基可燃材料的热力学性能,非等温反应动力学及安全性研究[J].火炸药学报,2017,40(2):19-23,32,6.
