内燃机工程2017，Vol.38Issue(2)：54-58,66,6.DOI:10.13949/j.cnki.nrjgc.2017.02.010
基于反应动力学模型的SCR催化剂氨存储特性研究
Research on Ammonia Storage Characteristics of SCR Catalyst Based on Reaction Kinetic Model
摘要
Abstract
A kinetic model for the adsorption-desorption of ammonia on SCR catalyst with single or dual active sites weas established.To this end, the model parameters were identified by ammonia adsorption-desorption tests on powdered SCR catalyst.The experimental results show that the adsorption-desorption process of ammonia on SCR catalyst can be described by the dual active sites reaction kinetic model than the single active site reaction kinetic model.The influences of temperature and ammonia inlet concentration on the ammonia storage capacity of SCR catalyst were studied based on the dual active sites reaction kinetic model.The simulation results show that the higher the temperature, the less the ammonia storage capacity of SCR catalyst, and the higher the ammonia inlet concentration, the higher the ammonia storage capacity with weak adsorption site, while the ammonia storage capacity with strong adsorption site remains the same.关键词
SCR催化剂/氨存储特性/反应动力学模型Key words
SCR catalyst/ammonia storage characteristics/reaction kinetic model分类
能源科技引用本文复制引用
戴佳伟,吴锋,姚栋伟,干旭波,魏铼,李杏文..基于反应动力学模型的SCR催化剂氨存储特性研究[J].内燃机工程,2017,38(2):54-58,66,6.基金项目
国家"八六三"高技术研究发展计划项目(2013AA065301) （2013AA065301）
