烟草科技2017，Vol.50Issue(3)：52-56,5.DOI:10.16135/j.issn1002-0861.2016.0317
拉曼光谱法快速测定电子烟烟液中的1,2-丙二醇和丙三醇
Rapid determination of 1,2-propylene glycol and glycerol in refill fluids for electronic cigarettes by Raman spectroscopy
摘要
Abstract
A simple and rapid Raman spectroscopy method for simultaneous determination of 1,2-propylene glycol and glycerol in refill fluids for electronic cigarettes was developed. Samples of 17 refill fluids were analyzed by a portable Raman spectrometer,and the data were compared with those determined by GC-MS. The results showed that:1)The standard curves of 1,2-propylene glycol and glycerol determined at the Raman intensity of 522 and 671 cm-1 possessed good correlation coefficients (R2 above 0.999) in the content range of 0.125-0.956 and 0.106-1.120 g/mL,respectively. The results of one sample t-test and independent sample t-test indicated that the Raman method was accurate. 2)The contents of 1,2-propylene glycol and glycerol in 17 refill fluids were in the range of 0.533-0.766 and 0.182-0.476 g/mL,respectively. The result of paired sample t-test showed that the data determined by Raman spectroscopy were consistent with those obtained by GC-MS at a confidence level of 95%. Without sample pretreatment,Raman spectroscopy method is simple to operate and more suitable for the rapid quantitative determination of 1,2-propylene glycol and glycerol in batches of refill fluids for electronic cigarettes.关键词
拉曼光谱/电子烟烟液/1,2-丙二醇/丙三醇Key words
Raman spectroscopy/Refill fluid for electronic cigarette/1,2-Propylene glycol/Glycerol分类
轻工纺织引用本文复制引用
李霞,温宝英,卢昕博,徐建,胡安福,蒋健,李剑锋,周国俊..拉曼光谱法快速测定电子烟烟液中的1,2-丙二醇和丙三醇[J].烟草科技,2017,50(3):52-56,5.基金项目
浙江中烟工业有限责任公司科技项目"电子烟中烟碱释放行为研究"(ZJZY2015A002). （ZJZY2015A002）
