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超支化聚酰胺-胺破乳剂的合成及应用

王海卫 徐昆 谭颖 路璀阁 那辉 王丕新 汪洋 刘秀生

应用化学2017,Vol.34Issue(4):423-429,7.
应用化学2017,Vol.34Issue(4):423-429,7.DOI:10.11944/j.issn.1000-0518.2017.04.160259

超支化聚酰胺-胺破乳剂的合成及应用

Synthesis and Application of Hyperbranched Poly(amido amine) Demulsifier

王海卫 1徐昆 2谭颖 1路璀阁 1那辉 1王丕新 3汪洋 1刘秀生4

作者信息

  • 1. 中国科学院长春应用化学研究所,生态环境高分子材料重点实验室 长春 130022
  • 2. 中国科学院大学 北京 100049
  • 3. 吉林大学化学学院 长春 130012
  • 4. 武汉材料保护所 武汉 430030
  • 折叠

摘要

Abstract

N-acryloyl-1,2-diaminoethane hydrochloridthe(ADE) was firstly synthesized, and then cationic hyperbranched poly(N-acryloyl-1,2-diaminoethane hydrochloride)(HADE) was prepared by Michael addition reaction of ADE and the structures were characterized in detail.The HADE was utilized as demulsifier for simulating oil/water(O/W) emulsion containing 5% mass fraction kerosene and the result indicates that the oil removal rate can be up to 95.6% at 50 ℃ when HADE demulsifier content ratio is 200 mg/L, impolying a good prospective of HADE demulsifier in demulsification and oil-removal.

关键词

超支化聚合物/O/W乳液/破乳剂/破乳机理

Key words

hyperbranched polymer/oil/water emulsion/demulsifier/demulsification mechanisms

分类

化学化工

引用本文复制引用

王海卫,徐昆,谭颖,路璀阁,那辉,王丕新,汪洋,刘秀生..超支化聚酰胺-胺破乳剂的合成及应用[J].应用化学,2017,34(4):423-429,7.

基金项目

吉林省科技发展计划项目(20140204083GX,20140204064SF,20140307007GX)Supported by Jilin Provincial Science and Technology Development Plant Project(No.20140204083GX, No.20140204064SF, No.20140307007GX) (20140204083GX,20140204064SF,20140307007GX)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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