化工进展2017,Vol.36Issue(5):1682-1689,8.DOI:10.16085/j.issn.1000-6613.2017.05.017
基于Aspen Plus用户模型技术的油页岩热解过程模拟
Simulation of oil shale pyrolysis using Aspen Plus user model
摘要
Abstract
It was used to build the oil shale pyrolysis model based on chemical structure,using Fortran language to compile mathematical model of the main components and embedding Aspen Plus based on user model.The main components of yield with the temperature change was simulated calculation.The accuracy of the results was verified by comparing document of the experimental data and simulation of the data.The results indicated that the simulation of the data for CO and CH4 agreed well with document of the experimental data.The analogue value of CO2 and shale oil had a good fit before about 600℃,while some deviations occurred after 600℃ due to the influence of decomposition of mineral substances.The simulation of the data for H2 in the beginning stages had a good fit with document of the experimental data,but the deviation degree slowly enlarged as time went on.Meanwhile,the yield of main components with time under different temperature was forecasted, It was found that the yield of main components first increased rapidly and then gradually stabilized at a constant value with the extension of time.When the temperature was relatively low,the yield of main components increased as time went by.When the pyrolysis temperature was further enhanced,the time required for organic matter decomposition was gradually reduced.The yield of the main component increased with the raise of pyrolysis temperature at the same time.关键词
油页岩/用户模型/AspenPlus/化学结构/模拟Key words
oil shale/user model/Aspen Plus/chemical structure/simulation分类
能源科技引用本文复制引用
柏静儒,李启凡,吴海涛,白章,王擎..基于Aspen Plus用户模型技术的油页岩热解过程模拟[J].化工进展,2017,36(5):1682-1689,8.基金项目
吉林省重点科技公关项目(20140204004SF). (20140204004SF)