有色金属科学与工程2017,Vol.8Issue(2):47-51,5.DOI:10.13264/j.cnki.ysjskx.2017.02.008
基于石墨烯量子点修饰电极的亚硝酸根电化学传感器
Nitrite electrochemical sensor based on graphene quantum dots modified electrode
摘要
Abstract
Material of grapheme quantum dots was dropped on the surface of glassy carbon electrode to form its film, and nitrite (NO2-) electrochemical sensor was prepared. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) were utilized to characterize grapheme quantum dots (GQDs). Meanwhile, electrochemical behavior of nitrite was researched by cyclic voltammetry (CV), differential pulse voltammetry(DPV)and current-time curve (I-T) on the surface of modified electrode. The experimental results show that electrochemical sensor exhibits a good electrocatalysis to NO2- and possesses a broad linear range in 1~29 μmol/L with detection limit of 3.33×10-7 mol/L (S/N=3). The electrochemical sensor shows the characteristics of wide detection range, low detection limit and good stability.关键词
石墨烯量子点/修饰电极/亚硝酸盐/电化学传感器Key words
graphene quantum dots/modified electrode/nitrite/electrochemical sensor分类
化学化工引用本文复制引用
黄海平,徐亮,岳亚锋,许方..基于石墨烯量子点修饰电极的亚硝酸根电化学传感器[J].有色金属科学与工程,2017,8(2):47-51,5.基金项目
国家自然科学基金资助项目(21465013,21005034) (21465013,21005034)
中国博士后科学基金面上项目(2014M551550) (2014M551550)
江西省自然科学青年科学基金项目(20114BAB213014) (20114BAB213014)
江西理工大学清江青年英才支持计划资助项目 ()