林产化学与工业2017，Vol.37Issue(2)：11-21,11.DOI:10.3969/j.issn.0253-2417-2017-02-002
固体催化剂在生物质合成乙酰丙酸和乙酰丙酸酯中的应用研究进展
Progress of Application of Solid Catalysts in Levulinic Acid and Alkyl Levulinates Produced from Biomass
摘要
Abstract
The synthetic pathways of levulinic acid and alkyl levulinates were introduced.The synthetic routes of levulinic acid mainly includes catalyzed hydrolysis of furfuryl alcohol, direct hydrolysis of biomass and hydrolysis of hemicellulose.The synthetic pathways of alkyl levulinate were esterification of levulinic acid, direct alcoholysis of biomass, alcoholysis of furfuryl alcohol and alcoholysis of 5-chloro methyl furfural.Recent research of solid catalysts used in conversion of biomass into levulinic acid and alkyl levulinates were reviewed, and the brief overview of the solid catalyst types that used in biomass conversion such as super acid, molecular sieve, heteropoly acid and resin was conducted.Furthermore, the development and application in the future of solid catalyst were also prospected.关键词
乙酰丙酸/乙酰丙酸酯/生物质/固体催化剂Key words
levulinic acid/alkyl levulinates/biomass/solid catalyst分类
化学化工引用本文复制引用
常春,邓琳,戚小各,白净,方书起..固体催化剂在生物质合成乙酰丙酸和乙酰丙酸酯中的应用研究进展[J].林产化学与工业,2017,37(2):11-21,11.基金项目
国家自然科学基金资助项目(21176227,U1404519) （21176227,U1404519）
