林产化学与工业2017，Vol.37Issue(2)：22-34,13.DOI:10.3969/j.issn.0253-2417-2017-02-003
纤维素催化转化制备C5/C6烷烃燃料的反应与催化体系的研究进展
Progress on Reaction and Catalyst for Production of C5/C6 Alkane Fuels from Cellulose by Catalytic Conversion
摘要
Abstract
The reactions and catalytic systems for the production of C5/C6 alkanes from cellulose or lignocellulosic biomass were summarized.The reaction pathways mainly included one-pot conversion of cellulose to alkanes by hydrolysis-hydrodeoxygenation;and hydrocarbon fuels produced from C6 platform compounds by hydrodeoxygenation.The reaction pathways and catalysts of alkanes production from raw lignocelluloses, cellulose, glucose and sorbitol were summarized.And the reaction pathways mainly included sorbitol, isosorbide, HMF and caprolactone routes.The metal-acid multifunctional catalysts were widely used;acid catalysts included metal oxides, zeolites, heteropoly acids, ionic liquid acid and inorganic acid, etc., and the metal catalysts were mainly Pd, Pt, Ni, Ru, Ir, etc.The metal Ru was popularly studied due to its excellent catalytic performance under the acidic hydrothermal environment.Finally, for the state-of-the-art technologies in the conversion of biomass to C5/C6 alkanes, the main uncertainties, bottlenecks and research needs were concluded and prospected.关键词
纤维素/催化/烷烃/水解/加氢脱氧Key words
cellulose/catalysis/alkane/hydrolysis/hydrodeoxygenation分类
化学化工引用本文复制引用
陈伦刚,刘勇,张兴华,张琦,王铁军,马隆龙..纤维素催化转化制备C5/C6烷烃燃料的反应与催化体系的研究进展[J].林产化学与工业,2017,37(2):22-34,13.基金项目
国家自然科学基金青年项目(51306189) （51306189）
广东省省级科技计划项目(2014A010106022) （2014A010106022）
中国科学院STS计划项目(KFJ-EW-STS-138) （KFJ-EW-STS-138）
