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高炉熔渣微晶玻璃的结构与性能研究

梅书霞 裴可鹏 何峰 刘小青 方德 杨虎 谢峻林

人工晶体学报2017,Vol.46Issue(4):698-704,7.
人工晶体学报2017,Vol.46Issue(4):698-704,7.

高炉熔渣微晶玻璃的结构与性能研究

Structure and Properties of Molten Blast Furnace Slag Glass-Ceramics

梅书霞 1裴可鹏 1何峰 1刘小青 1方德 1杨虎 1谢峻林1

作者信息

  • 1. 武汉理工大学硅酸盐建筑材料国家重点实验室,武汉 430070
  • 折叠

摘要

Abstract

Molten slag has a large amount of heat and slag.The preparation of glass-ceramics by melting method using molten slag can utilize the furnace slag efficiently.The parent glass with stable performance was prepared by mixed-melting at high temperature.The heat treatment process of the parent glass was determined by differential scanning calorimetry (DSC).The microstructure and properties of the glass-ceramics were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), scanning electron microscopy (FE-SEM).The results indicate that the increase of F content in the parent glass promot the nucleation and crystal growth and decrease the nucleation and crystallization temperature of the glass ceramics.The main crystal phase of glass-ceramics is fluorite at the low heat treatment temperature, nepheline and fluorite are precipitated simultaneously at high heat treatment temperature.The content and type of crystalline phase significantly influence the flexural strength and hardness of the glass-ceramics, the microhardness is up to 585.68 MPa, the flexural strength is up to 126.21 MPa.

关键词

微晶玻璃/熔融法/高炉熔渣/热处理/力学性能

Key words

glass-ceramics/melting method/molten blast furnace slag/heat treatment/mechanical property

分类

化学化工

引用本文复制引用

梅书霞,裴可鹏,何峰,刘小青,方德,杨虎,谢峻林..高炉熔渣微晶玻璃的结构与性能研究[J].人工晶体学报,2017,46(4):698-704,7.

基金项目

"十三五"国家重点研发计划项目(2016YFB0601304) (2016YFB0601304)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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