物理化学学报2017，Vol.33Issue(5)：960-967,8.DOI:10.3866/PKU.WHXB201702086
手性布洛芬对映体的选择性光电化学氧化
Selective Photoelectrochemical Oxidation of Chiral Ibuprofen Enantiomers
摘要
Abstract
The photoelectrochemical method was combined with the in-situ molecular imprinting technique.Using the chiral ibuprofen enantiomers (S-ibuprofen and R-ibuprofen) as template molecules,S-ibuprofen and R-ibuprofen molecular imprinting sites were constructed on the surface of monocrystalline TiO2 nanorods.The imprinted electrodes were capable of selective recognition and catalytic oxidation of S-ibuprofen and R-ibuprofen.The morphology,structure,and composition of the electrode were characterized using scanning electron microscopy (SEM),transmission electron microscopy (TEM),X-ray diffraction (XRD),and Raman spectroscopy.The electron transfer resistance of the electrode surface was studied with electrochemical impedance spectroscopy.The photoelectrochemical recognition and degradation were measured photoelectrochemically using the prepared imprinted electrodes as the working electrode.The TiO2 prepared was a single crystal nanorod array.The imprinted sites were successfully constructed on the surface of TiO2 nanorods and had shape selective adsorption capacities.The selective recognition and selective oxidative degradation of chiral ibuprofen enantiomers on the surface of artificial photoelectrocatalysts were realized for the first time.关键词
布洛芬/单晶二氧化钛/光电化学识别/择形吸附/选择性氧化降解Key words
Ibuprofen/Monocrystalline TiO2/Photoelectrochemical recognition/Shape selective adsorption/Selective oxidative degradation分类
化学化工引用本文复制引用
代卫国,何丹农..手性布洛芬对映体的选择性光电化学氧化[J].物理化学学报,2017,33(5):960-967,8.基金项目
The project was supported by the International Science and Technology Cooperation Program of China (2015CB931902).国家国际科技合作专项(2015CB931902)资助项目 （2015CB931902）
