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硅橡胶/改性蒙脱土复合材料的制备及其性能研究

夏艳平 耿浩然 顾艺 曹峥 陶国良

中国塑料2017,Vol.31Issue(5):26-30,5.
中国塑料2017,Vol.31Issue(5):26-30,5.DOI:10.19491/j.issn.1001-9278.2017.05.006

硅橡胶/改性蒙脱土复合材料的制备及其性能研究

Preparation and Performance of Silicone Rubber/Modified Montmorillonite Composites

夏艳平 1耿浩然 2顾艺 1曹峥 1陶国良1

作者信息

  • 1. 常州大学材料科学与工程学院,江苏常州213164
  • 2. 常州大学江苏省环境友好高分子材料重点实验室,江苏常州213164
  • 折叠

摘要

Abstract

A surface modification for montmorillonite (MMT) was conducted by using di-octadecyl dimethyl ammonium chloride,and then the methyl vinyl silicone rubber (MVQ)-based composites with modified MMT and the pristine one were prepared by a melt mixing method.The effect of room temperature mixing and melting mixing methods on mechanical properties,thermal performance and morphology of the composites were investigated.The results indicated that the interlamellar spacing of MMT was improved from 1.25 to 3.97 nm after modification.The melt mixing method was more advantageous for the formation of intercalated structure in comparison with the room temperature mixing method.The composites prepared by melt mixing also achieved higher tensile strength,and a maximum value of 6.0 MPa when 30 phr of modified MMT was incorporated.However,its thermal stability tended to decrease.

关键词

甲基乙烯基硅橡胶/双十八烷基二甲基氯化铵/蒙脱土/改性/插层/熔融混炼

Key words

methyl vinyl silicone rubber/di-octadecyl dimethyl ammonium chloride/montmorillonite/modified/intercalation/melt mixing

分类

化学化工

引用本文复制引用

夏艳平,耿浩然,顾艺,曹峥,陶国良..硅橡胶/改性蒙脱土复合材料的制备及其性能研究[J].中国塑料,2017,31(5):26-30,5.

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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