高等学校化学学报2017，Vol.38Issue(4)：598-605,8.DOI:10.7503/cjcu20160684
咪唑螯合硼离子液体的合成、表征及摩擦学性能
Synthesis, Characterization and Tribological Properties of Imidazol Cheat Boron Ionic Liquids with Different Alkyl Length
摘要
Abstract
Four environmental-friendly ionic liquids containing imidazol cations with different alkyl chain lengths and bis(salicylato)borate anion were synthesized.Their structures were characterized by NMR, ICP-OES and tribo-performance was studied on four-ball machine and SEM-EDX as well.Tribological properties are largely influenced by alkyl chain lengths.CnMImBScB(n=2,4,6,8) have excellent friction reducing properties, in particular, the coefficient of friction and wear scar diameter lubricated by PEG200 under 392N reduce 58.46% and 20.5%, respectively, when mass fraction of 2% C8MImBScB is introduced.The elemental mapping of worn surfaces reveal that the formation of cheat boron ionic liquids constitutes a tribo-chemical thin film, which not only protect the contact surface against the wear at some extent but also reduces the friction significantly.关键词
环境友好型/硼/离子液体/抗磨损/减摩Key words
Environmental-friendly/Boron/Ionic liquid/Anti-wear/Anti-friction分类
化学化工引用本文复制引用
张云潇,商旺吉,孙俪文,刘丹,童丁毅,蔡涛,刘升高..咪唑螯合硼离子液体的合成、表征及摩擦学性能[J].高等学校化学学报,2017,38(4):598-605,8.基金项目
国家自然科学基金(批准号:21404114)、中国博士后科学基金面上项目(批准号:2014M561797)、浙江省博士后科研项目择优资助项目(批准号:BSH1502162)和宁波市自然科学基金(批准号:2015A610051)资助.Supported by the National Natural Science Foundation of China(No.21404114), the China Postdoctoral Science Foundation(No.2014M561797), the Zhejiang Postdoctoral Sustentation Fund, China(No.BSH1502162) and the Natural Science Foundation of Ningbo, China(No.2015A610051). （批准号:21404114）
