南京理工大学学报(自然科学版)2017,Vol.41Issue(2):232-238,7.DOI:10.14177/j.cnki.32-1397n.2017.41.02.015
二维锌配合物的合成、结构及性能研究
Synthesis,structure and property of 2D znic complex
摘要
Abstract
A new 2D complex with the formula {[Zn6(imb)4(btc)4]·7.5H2O}n(1)is synthesized through the solvothermal reaction of Zn(NO3)2·6H2O,2-(1H-imidazol-1-methyl)-1H-benzimidazole(imb)and sodium benzene-1,2,3-tricarboxylate(Na3btc)at 120 ℃,and it is structurally characterized by the elemental analysis,the infrared spectroscopy(IR)and the thermogravimetric analysis.The single-crystal X-ray analysis reveals that the complex 1 crystallizes in the monoclinic space group P21/c.Upon excitation at 312 nm,complex powders exhibits intense emission at 422 nm and room temperature for the solid state.关键词
Zn(Ⅱ)-配合物/2-(1H-咪唑-1-甲基)-1H-苯并咪唑/1,2,3-苯三甲酸钠/晶体结构/热稳定性/荧光性能Key words
Zn(Ⅱ)-complex/2-(1H-imidazol-1-methyl)-1H-benzimidazole/sodium benzene-1/2/3-tricarboxylate/crystal structure/thermal stability/fluorescence property分类
化学化工引用本文复制引用
黄秋颖,林肖漪,孟祥茹..二维锌配合物的合成、结构及性能研究[J].南京理工大学学报(自然科学版),2017,41(2):232-238,7.基金项目
国家自然科学基金(J1210060) (J1210060)
河南省教育厅基础与前沿技术研究计划资助项目(16B150002) (16B150002)
河南省科技厅基础与前沿技术研究项目(162300410206) (162300410206)
河南省科技攻关项目(172102210128) (172102210128)